WEKO3
アイテム
{"_buckets": {"deposit": "f05fb12d-e3f0-4ac2-8a49-f43117b57132"}, "_deposit": {"created_by": 13, "id": "9355", "owners": [13], "pid": {"revision_id": 0, "type": "depid", "value": "9355"}, "status": "published"}, "_oai": {"id": "oai:uec.repo.nii.ac.jp:00009355", "sets": ["6"]}, "author_link": ["25492", "25485", "25484", "25489", "25495", "25487", "25488", "25494", "25486", "25490", "25491", "25493"], "item_10001_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-08-22", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "33", "bibliographicPageEnd": "27744", "bibliographicPageStart": "27734", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{}, {"bibliographic_title": "ACS Applied Materials \u0026 Interfaces", "bibliographic_titleLang": "en"}]}]}, "item_10001_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "It is hard to directly visualize spectroscopic and atomic–nanoscopic information on the degraded Pt/C cathode layer inside polymer electrolyte fuel cell (PEFC). However, it is mandatory to understand the preferential area, sequence, and relationship of the degradations of Pt nanoparticles and carbon support in the Pt/C cathode layer by directly observing the Pt/C cathode catalyst for the development of next-generation PEFC cathode catalysts. Here, the spectroscopic, chemical, and morphological visualization of the degradation of Pt/C cathode electrocatalysts in PEFC was performed successfully by a same-view combination technique of nano-X-ray absorption fine structure (XAFS) and transmission electron microscopy (TEM)/scanning TEM–energy-dispersive spectrometry (EDS) under a humid N2 atmosphere. The same-view nano-XAFS and TEM/STEM–EDS imaging of the Pt/C cathode of PEFC after triangular-wave 1.0–1.5 VRHE (startup/shutdown) accelerated durability test (tri-ADT) cycles elucidated the site-selective area, sequence, and relationship of the degradations of Pt nanoparticles and carbon support in the Pt/C cathode layer. The 10 tri-ADT cycles caused a carbon corrosion to reduce the carbon size preferentially in the boundary regions of the cathode layer with both electrolyte and holes/cracks, accompanied with detachment of Pt nanoparticles from the degraded carbon. After the decrease in the carbon size to less than 8 nm by the 20 tri-ADT cycles, Pt nanoparticles around the extremely corroded carbon areas were found to transform and dissolve into oxidized Pt2+–O4 species.", "subitem_description_type": "Abstract"}]}, "item_10001_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Chemical Society "}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1021/acsami.8b04407", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "関連サイト", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acsami.8b04407", "subitem_relation_type_select": "DOI"}}]}, "item_10001_rights_15": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "©2018 American Chemical Society "}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1944-8244", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takao, Shinobu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25484", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sekizawa, Oki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25485", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Samjeské, Gabor", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25486", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kaneko, Takuma", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25487", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Higashi, Kotaro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25488", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshida, Yusuke", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25489", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Zhao, Xiao", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25490", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakata, Tomohiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25491", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamamoto, Takashi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25492", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Gunji, Takao", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25493", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uruga, Tomoya", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25494", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Iwasawa, Yasuhiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25495", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-09-24"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACS Appl. Mater. Interfaces_rev2_Iwasawa docx.pdf", "filesize": [{"value": "2.8 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2800000.0, "url": {"label": "ACS Appl. Mater. Interfaces_rev2_Iwasawa docx", "url": "https://uec.repo.nii.ac.jp/record/9355/files/ACS Appl. Mater. Interfaces_rev2_Iwasawa docx.pdf"}, "version_id": "c35ad2b2-3c95-47e0-b024-a38a541872f6"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Same-view imaging", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Nano-XAFS/STEM-EDS", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "PEFC Pt/C cathode", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pt and carbon degradations", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Degradation sequence", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Observation of Degradation of Pt and Carbon Support in Polymer Electrolyte Fuel Cell Using Combined Nano-X-ray Absorption Fine Structure and Transmission Electron Microscopy Techniques", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Observation of Degradation of Pt and Carbon Support in Polymer Electrolyte Fuel Cell Using Combined Nano-X-ray Absorption Fine Structure and Transmission Electron Microscopy Techniques", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "13", "path": ["6"], "permalink_uri": "https://uec.repo.nii.ac.jp/records/9355", "pubdate": {"attribute_name": "公開日", "attribute_value": "2019-09-24"}, "publish_date": "2019-09-24", "publish_status": "0", "recid": "9355", "relation": {}, "relation_version_is_last": true, "title": ["Observation of Degradation of Pt and Carbon Support in Polymer Electrolyte Fuel Cell Using Combined Nano-X-ray Absorption Fine Structure and Transmission Electron Microscopy Techniques"], "weko_shared_id": -1}
Observation of Degradation of Pt and Carbon Support in Polymer Electrolyte Fuel Cell Using Combined Nano-X-ray Absorption Fine Structure and Transmission Electron Microscopy Techniques
https://uec.repo.nii.ac.jp/records/9355
https://uec.repo.nii.ac.jp/records/935580f4990f-e248-4ab1-b557-154b0fbc2178
名前 / ファイル | ライセンス | アクション |
---|---|---|
ACS Appl. Mater. Interfaces_rev2_Iwasawa docx (2.8 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2019-09-24 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Observation of Degradation of Pt and Carbon Support in Polymer Electrolyte Fuel Cell Using Combined Nano-X-ray Absorption Fine Structure and Transmission Electron Microscopy Techniques | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Same-view imaging | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Nano-XAFS/STEM-EDS | |||||
キーワード | ||||||
言語 | en | |||||
主題 | PEFC Pt/C cathode | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Pt and carbon degradations | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Degradation sequence | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Takao, Shinobu
× Takao, Shinobu× Sekizawa, Oki× Samjeské, Gabor× Kaneko, Takuma× Higashi, Kotaro× Yoshida, Yusuke× Zhao, Xiao× Sakata, Tomohiro× Yamamoto, Takashi× Gunji, Takao× Uruga, Tomoya× Iwasawa, Yasuhiro |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | It is hard to directly visualize spectroscopic and atomic–nanoscopic information on the degraded Pt/C cathode layer inside polymer electrolyte fuel cell (PEFC). However, it is mandatory to understand the preferential area, sequence, and relationship of the degradations of Pt nanoparticles and carbon support in the Pt/C cathode layer by directly observing the Pt/C cathode catalyst for the development of next-generation PEFC cathode catalysts. Here, the spectroscopic, chemical, and morphological visualization of the degradation of Pt/C cathode electrocatalysts in PEFC was performed successfully by a same-view combination technique of nano-X-ray absorption fine structure (XAFS) and transmission electron microscopy (TEM)/scanning TEM–energy-dispersive spectrometry (EDS) under a humid N2 atmosphere. The same-view nano-XAFS and TEM/STEM–EDS imaging of the Pt/C cathode of PEFC after triangular-wave 1.0–1.5 VRHE (startup/shutdown) accelerated durability test (tri-ADT) cycles elucidated the site-selective area, sequence, and relationship of the degradations of Pt nanoparticles and carbon support in the Pt/C cathode layer. The 10 tri-ADT cycles caused a carbon corrosion to reduce the carbon size preferentially in the boundary regions of the cathode layer with both electrolyte and holes/cracks, accompanied with detachment of Pt nanoparticles from the degraded carbon. After the decrease in the carbon size to less than 8 nm by the 20 tri-ADT cycles, Pt nanoparticles around the extremely corroded carbon areas were found to transform and dissolve into oxidized Pt2+–O4 species. | |||||
書誌情報 |
en : ACS Applied Materials & Interfaces 巻 10, 号 33, p. 27734-27744, 発行日 2018-08-22 |
|||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1944-8244 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/acsami.8b04407 | |||||
権利 | ||||||
権利情報 | ©2018 American Chemical Society | |||||
関連サイト | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acsami.8b04407 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |