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Hidden Heterometallic Interaction Emerging from Resonant Inelastic X-ray Scattering in Luminescent Tb–Pt Molecules
https://uec.repo.nii.ac.jp/records/10346
https://uec.repo.nii.ac.jp/records/10346430bda9a-d098-42d8-aa21-0365ec7bfa83
名前 / ファイル | ライセンス | アクション |
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JPCC_rev.pdf (682.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2023-05-13 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Hidden Heterometallic Interaction Emerging from Resonant Inelastic X-ray Scattering in Luminescent Tb–Pt Molecules | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yoshida, Takefumi
× Yoshida, Takefumi× Shabana, Ahmed× Izuogu, David Chukwuma× Fuku, Kentaro× Sato, Tetsu× Zhang, Haitao× Yamamoto, Yukina× Kamata, Jun× Ohmagari, Hitomi× Hasegawa, Miki× Cosquer, Goulven× Takaishi, Shinya× Kaneko, Takuma× Uruga, Tomoya× Iwasawa, Yasuhiro× Yamashita, Masahiro |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Theoretical calculations are typically utilized for examining intermetallic interactions. However, to validate the theory, experimental confirmation of the existence of these interactions is necessary. We synthesized new heterometallic Ln–Pt complexes, NEt_4{[Pt(PhSAc)_4]Ln[(PhSAc)_4Pt]}·2DMF (Ln: lanthanoid = Gd (1), Tb (2), Dy (3), PhSAc = benzothioacetate, NEt_4 = tetraethylammonium), in which both diamagnetic Pt(II) ions interact with the central Ln(III) ion. Typically, these interactions are not detected because the distance between Ln and Pt atoms (∼3.6 Å) is much larger than the covalent radius (∼3.3 Å) and ionic radius (∼3.10 Å). Pt–LIII resonant inelastic X-ray scattering (RIXS) analysis was conducted to experimentally confirm the unique influence of the hidden Ln–Pt interaction on the luminescence of the Tb–Pt molecule, where the interaction induced emission properties in the Tb and Pt ions, with high quantum yield (59%). Quantum theory of atoms in molecules (QTAIM) analysis was also used to confirm the experimental results. RIXS analysis allowed the identification of several distinctive characteristics of the coordination environment, including the existence of heterometallic interactions, that affected the observed luminescence. | |||||
書誌情報 |
en : The Journal of Physical Chemistry C 巻 126, 号 18, p. 7973-7979, 発行日 2022-05-12 |
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出版者 | ||||||
出版者 | American Chemical Society (ACS) | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 19327447 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/acs.jpcc.2c01396 | |||||
権利 | ||||||
権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry C, copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see (https://doi.org/10.1021/acs.jpcc.2c01396). | |||||
関連サイト | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acs.jpcc.2c01396 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |